A wide variety of nitro toluene options are available to you, such as industrial grade, electron grade, and medicine grade. Ou chemical safety data no longer updated more details. The carcinogen selector gives researchers the ability to select carcinogens by the mouse organs that they promote cancer in. Voranate t80 type i and type ii tdi are part of the family of quality aromatic isocyanates available from dow. The crystals will start to melt slowly, so put them into a storage container fast. Thermodynamic properties of intermediate and radical species are estimated by group additivity. Dispose of contentscontainer according to section of the sds.
Material safety data sheet nitrobenzene msds section 1. If it contacts the skin, the area should be washed with soap. Onitrotoluene is toxic by inhalation, ingestion and skin aborption, targeting the blood, central nervous system, skin, and gastrointestinal tract. The information contained in this material safety data sheet is based upon available data and believed to be correct. There are 54 suppliers who sells nitro toluene on, mainly located in asia. Rapporteur for the risk assessment of 2,4 dinitrotoluene is spain. Hazardous combustion products hazardous decomposition products formed under fire conditions. Now if youre adding ch3cl with friedelcraftsalcl3 reaction, youll have the m nitro toluene, because the nitro radical is a secondary substituent, and all the ring processes will end in meta form. Trinitrotoluene tnt 118967 not available section 3. Tnt, or more specifically 2,4,6trinitrotoluene, is a chemical compound with the formula c 6 h 2 no 2 3 ch 3. Sigmaaldrich 244511 page 3 of 8 suitable extinguishing media use water spray, alcoholresistant foam, dry chemical or carbon dioxide. Nmethylnnitrosoptoluenesulfonamide msds msdsdigital. Disclaimer the sds samples above are collected from the internet by chemblink and displayed here for the tutorial purpose only.
A detailed chemical kinetic mechanism for gas phase combustion of 2,4,6trinitrotoluene tnt has been developed to explore problems of explosive performance and of soot formation during the destruction of munitions. Structure, properties, spectra, suppliers and links for. The principle application involves its sulfonation to give the 4nitrotoluene2sulfonic acid with the so 3 h group adjacent to methyl. Pnitro tolueneosulfonic acid, dye intermediate, chemicals. It is an intermediate in the production of various dyes. Material safety data sheet nitrobenzene pure section 1. Carcinogen selector endocrine system mammary gland. Symptoms include, anoxia, weakness or dizziness, nausea and vomiting.
Excerpt from erg guide 152 substances toxic combustible. Nitrotoluene definition of nitrotoluene by merriamwebster. A mononitrotoluene carrying a nitro group at position 3. Both type i and type ii are a mixture of 2,4 and 2,6isomers of tdi in a ratio, by weight, of 80 percent and 20 percent, respectively. It has a role as an environmental contaminant and a carcinogenic agent. Show this safety data sheet to the doctor in attendance. The information in cameo chemicals comes from a variety of data sources.
Nmethylnnitrosoptoluenesulfonamide msds special notice. The substance identity section is calculated from substance identification information from all echa databases. The explosive yield of tnt is considered to be the standard. Special protective equipment for firefighters wear self contained breathing apparatus for fire fighting if necessary. Identification of the substancemixture and of the companyundertaking 1. Avoid runoff into storm sewers and ditches which lead to waterways. Di nitro toluene dnt is a solid crystalline organic compound with pale yellow colour and fabricated as precursor for toluene diisocyanate tdi and trinitrotoluene tnt. Although kidney toxicity has not been common in cases of occupational toluene exposure, there has been at least one report of renal toxicity following a 40year occupational toluene exposure. Page 4 of 7 msds toluene di isocyanate incompatibles such as moisture. Department of transportation hazard labels, and a general description of the chemical.
This pale yellow crystalline solid is well known as a precursor to trinitrotoluene but is mainly produced as a precursor to toluene diisocyanate. In case of skin contact wash off with soap and plenty of water. Di nitro toluene market size will witness a significant growth due to its increasing applications in various industries including chemical, plastics, explosives and automotive. As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters 150 feet for liquids and at least 25 meters 75 feet for solids. Toluene, a flammable liquid with a pungent odor, is widely employed as an organic solvent. Demand for luxury cars namely lexus and bmw have grown by over 15% in 2016 with increase in disposable income that has given a positive outlook to di nitro toluene market. September 8, 2009 information in this msds is from available published sources and is believed to be accurate. The chemical identifier fields include common identification numbers, the nfpa diamond u.
Nitration of toluene give mono, di, and trinitrotoluene, all of which are widely used. Aniline material safety data sheet cas no 62533 sdsmsds. Material safety data sheet trinitrotoluene tnt msds. Application toluene undergoes alkylation in the presence of modified zsm zeolite socony mobil5class zeolite catalysts to form pxylene with high selectivity. Chemspider does not currently have any image data for this record. Read the product manufacturers material safety data. All explosives are dangerous and must be handled carefully and used following approved safety.
Firstaid measures general advice if symptoms persist, call a physician. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. Section 6 accidental release measures general information. Jun 18, 2010 for the best answers, search on this site if you treat the benzene with hno3,h2so4 for the first step, youll have c6h5no2. Multifunctional magnetic resins having high surface area and ion exchange efficiency gma301 and gma302 were developed and were tested for the desorption of 2nitrotolene. Incompatible with oxidizing agents, strong bases,sulfuric acid, reducing agents, hydrogen, sodium.
Slowly combine 150 ml of 68% nitric acid with 180 ml of sulfuric acid. Page 1 of 10 safety data sheet toluene diisocyanate. The top countries of suppliers are china, india, from which the percentage of nitro toluene supply is 87%, 12% respectively. If inhaled if breathed in, move person into fresh air. Panoli intermediates manufacturers and exporters of dye intermediate, chemicals manufacturer, industrial chemicals manufacturers, chemicals supplier, industrial dye intermediate, supplier of chemicals, chemical exporter, chemicals suppliers, industrial chemicals, dye intermediate manufacturer, indian industrial chemicals, industrial chemicals, industrial chemicals and dye, integrated. Vinmar international is a global marketing, distribution and project development company that brings value to the worlds leading producers and users of petrochemical products through tailored business solutions. The information provided in this safety data sheet is correct to the best of our knowledge, information and belief at the date of its publication. Di nitro toluene market size industry trends analysis. Take measures to prevent the build up of electrostatic. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If it contacts the eye, the eye should be irrigated immediately. Safety data sheet according to 29cfr19101200 and ghs rev. No warranty, express or implied, is made and labchem inc. This pale yellow crystalline solid is well known as a precursor to trinitrotoluene tnt but is mainly produced as a precursor to toluene diisocyanate.
The substance identifiers displayed in the infocard are the best available substance name, ec number, cas number andor the. It is also used as a precursor for synthesizing benzene. Skin contact wash off immediately with plenty of water for at least 15 minutes. For small spills of 2nitrotoluene, take up with vermiculite, dry sand, or earth and place into containers for later disposal. Sds of 3nitrooxylene, safety data sheets, cas 83410. These are primarily used to manufacture polyurethane foams. Rapporteur for the risk assessment of 2,4dinitrotoluene is spain. Toluene is mainly used as a precursor to benzene via hydrodealkylation. The user must determine suitability of this information for his. Since that time new data have become available, which have been incorporated in this monograph,and taken into consideration in the present evaluation. Sigmaaldrich offers a number of 2,6dichlorotoluene products. Absorb spill using an absorbent, noncombustible material such as earth, sand, or vermiculite. Sds of 2,4dinitrotoluene, safety data sheets, cas 121142. Identification of the substancemixture and of the company.
Pour 156 ml of toluene into a reflux apparatus with open pressure equalized addition funnel, place the flask in saltice slush. This pale yellow crystalline solid is well known as a precursor to. This yellow solid is sometimes used as a reagent in chemical synthesis, but it is best known as an explosive material with convenient handling properties. The national response center database contains reports of two spills reported as onitrotol. Safety data sheet northwest missouri state university. Dike to prevent land spills of 3nitrotoluene from entering water sources or sewers, and take up by absorbing the material in vermiculite, dry sand, or earth. Environmental releases in pounds of dinitrotoluene mixed. General description 2nitrotoluene is a nitroaromatic compound. However, we make no warranty of merchantability or any other. Together with other isomers, 4nitrotoluene is prepared by nitration of toluene. H410 very toxic to aquatic life with long lasting effects.
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